this worked on XP for some old skool games I wanted to play.
Right click on the shortcut for your game/program then click the compatability tab. Then you can choose how you want to run it ie: display settings and colours, under a different operating system.
If that doesnt work then you could download and use an emulation program called Dosbox and run it from there.
http://www.dosbox.com/information.php?page=0
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