Yes - 'you' are always first in the listing and usually the listing is alphabetical. Bear in mind that a username which start with odd characters such as underscore or colons will precede usernames with a numerical start - some times capitalised usernames precede lowercase names.
This is the case if you view the who's online list - http://forum.caithness.org/online.php
Not sure why it is not 'alphabetical' here - it is on other forums.
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